Preheat oven to 350°F and prepare a 9x9 inch baking pan with non-stick spray or parchment paper.
Roughly chop the semi-sweet chocolate and place into a microwave-safe bowl.
Slice the butter into smaller pieces and add to the chocolate. Microwave for 1 minute, stir, then microwave another 30 seconds. Stir thoroughly until melted and combined.
Add granulated sugar to the chocolate mixture and stir well to combine.
Mix in vanilla extract, eggs, and salt until batter is smooth and well incorporated.
Stir in the sourdough starter until the batter is smooth and even.
Pour batter into the prepared pan and bake for 25 to 28 minutes or until a toothpick inserted comes out with a few moist crumbs. Avoid overbaking for fudgy texture.
Notes
These brownies are best enjoyed fresh but develop an even richer, fudgier flavor when cold. Use parchment paper for easy removal.